Paper · 2026 · Next Materials

Ultrasonication-engineered urea nanomaterials: Chemical and morphological transformation toward enhanced fertilizer performance

Aulia Dewi Rosanti; Fahmi Hidayat; Widyana Rahmatika; et al.

15
claims
30
verbatim quotes
0
citations
2
research areas
✓
Open access · cc-by

Abstract

Conventional urea fertilizers are highly susceptible to nitrogen losses through volatilization and leaching, resulting in low nitrogen-use efficiency (NUE) and increased environmental impacts. Although nano urea has emerged as a promising alternative, comparative studies on ultrasonication-engineered nano urea systems and their integration with conventional fertilization strategies remain limited. In this study, urea nanopowder (UNS) and urea nanofluid (UNF) were synthesized via ultrasonication-assisted processing using a urea–trisodium citrate precursor system, followed by physicochemical characterization and agronomic evaluation in sweet corn (Zea mays var. saccharata). Ultrasonication at 30 kHz and 200 W successfully produced nanoscale particles with average diameters of 9.4 nm for UNS and 7.3 nm for UNF. FTIR and FESEM–EDX analyses confirmed ultrasonication-induced modifications in molecular interactions, surface morphology, elemental distribution, and particle stabilization behavior. Field evaluation showed no significant differences in vegetative growth parameters (p > 0.05), whereas yield-related traits were significantly improved (p < 0.05). The hybrid formulation consisting of 60% UNS and 40% conventional urea (P6) achieved the highest productivity of 26.97 t ha⁻¹ , representing a 9.2% increase compared with the conventional urea treatment alone (24.71 t ha⁻¹) and a 30.7% increase relative to the 100% UNS treatment (20.64 t ha⁻¹). Similarly, the UNF-based hybrid treatment produced yields of up to 25.73 t ha⁻¹ . Nano urea application also enhanced chlorophyll content, leaf thickness, and nitrogen uptake efficiency. Notably, standalone UNF exhibited the highest NUE (90.95%), indicating more efficient initial nitrogen synchronization, whereas UNS provided a more sustained nitrogen release that promoted biomass accumulation and yield formation. The improved agronomic performance was attributed to enhanced surface interactions, controlled nutrient release, and reduced nitrogen loss. Furthermore, the hybrid nano urea strategy enabled a 60% reduction in conventional urea application without compromising productivity, highlighting its potential as a sustainable fertilization approach for enhancing NUE and supporting environmentally responsible crop production.

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Claims 15

Observationobservedoriginal resultmeasured

Claim · model-written summary

Ultrasonication at 30 kHz and 200 W produced UNS particles with an average diameter of 9.4 nm.

Treatment
Ultrasonication at 30 kHz and 200 We3
Outcome
average diameterse3
Value
9.4 nme3
Qualifier
for UNSe3

Not reportedTaxon

Verbatim

e3

“Ultrasonication at 30 kHz and 200 W successfully produced nanoscale particles with average diameters of 9.4 nm for UNS and 7.3 nm for UNF”

✓ located verbatim in the source · abstract, characters 681–818 · show in text ↑

schema checkedfield values found in the cited quotesPermalinkReport an issue

Observationobservedoriginal resultmeasured

Claim · model-written summary

Ultrasonication at 30 kHz and 200 W produced UNF particles with an average diameter of 7.3 nm.

Treatment
Ultrasonication at 30 kHz and 200 We3
Outcome
average diameterse3
Value
7.3 nme3
Qualifier
for UNFe3

Not reportedTaxon

Verbatim

e3

“Ultrasonication at 30 kHz and 200 W successfully produced nanoscale particles with average diameters of 9.4 nm for UNS and 7.3 nm for UNF”

✓ located verbatim in the source · abstract, characters 681–818 · show in text ↑

schema checkedfield values found in the cited quotesPermalinkReport an issue

Observationobservedoriginal resultmeasured

Claim · model-written summary

FTIR and FESEM-EDX confirmed ultrasonication-induced modifications in molecular interactions, surface morphology and elemental distribution.

Treatment
ultrasonicatione4
Outcome
molecular interactions, surface morphology, elemental distributione4

Not reportedTaxon

Verbatim

e4

“FTIR and FESEM–EDX analyses confirmed ultrasonication-induced modifications in molecular interactions, surface morphology, elemental distribution, and particle stabilization behavior”

✓ located verbatim in the source · abstract, characters 820–1002 · show in text ↑

schema checkedfield values found in the cited quotesPermalinkReport an issue

Observationobservedoriginal resultmeasured

Claim · model-written summary

FTIR and FESEM-EDX confirmed ultrasonication-induced modifications in particle stabilization behavior.

Treatment
ultrasonicatione4
Outcome
particle stabilization behaviore4

Not reportedTaxon

Verbatim

e4

“FTIR and FESEM–EDX analyses confirmed ultrasonication-induced modifications in molecular interactions, surface morphology, elemental distribution, and particle stabilization behavior”

✓ located verbatim in the source · abstract, characters 820–1002 · show in text ↑

schema checkedfield values found in the cited quotesPermalinkReport an issue

Intervention effectobservedoriginal resultno effectnot significant (as stated)measured

Claim · model-written summary

Field evaluation of UNS and UNF showed no significant difference in vegetative growth parameters in sweet corn.

Taxon
sweet corne0
Treatment
urea nanopowder (UNS) and urea nanofluid (UNF)e2
Outcome
vegetative growth parameterse1
Direction
no significant differencese1
Qualifier
p > 0.05e1

Not reportedComparator

Verbatim

e0

“agronomic evaluation in sweet corn (Zea mays var. saccharata)”

✓ located verbatim in the source · abstract, characters 618–679 · show in text ↑
e1

“Field evaluation showed no significant differences in vegetative growth parameters (p > 0.05)”

✓ located verbatim in the source · abstract, characters 1004–1097 · show in text ↑
e2

“urea nanopowder (UNS) and urea nanofluid (UNF) were synthesized via ultrasonication-assisted processing”

✓ located verbatim in the source · abstract, characters 416–519 · show in text ↑
Intervention effectobservedoriginal resultpositivesignificant (as stated)measured

Claim · model-written summary

Nano urea treatments significantly improved yield-related traits of sweet corn in the field.

Taxon
sweet corne0
Treatment
urea nanopowder (UNS) and urea nanofluid (UNF)e2
Outcome
yield-related traitse5
Direction
improvede5
Qualifier
p < 0.05e5

Not reportedComparator

Verbatim

e0

“agronomic evaluation in sweet corn (Zea mays var. saccharata)”

✓ located verbatim in the source · abstract, characters 618–679 · show in text ↑
e2

“urea nanopowder (UNS) and urea nanofluid (UNF) were synthesized via ultrasonication-assisted processing”

✓ located verbatim in the source · abstract, characters 416–519 · show in text ↑
e5

“yield-related traits were significantly improved (p < 0.05)”

✓ located verbatim in the source · abstract, characters 1107–1166 · show in text ↑
Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

The hybrid of 60% UNS and 40% conventional urea (P6) achieved the highest productivity, 26.97 t/ha, in sweet corn.

Taxon
sweet corne0
Treatment
hybrid formulation consisting of 60% UNS and 40% conventional urea (P6)e6
Outcome
productivitye6
Direction
higheste6
Value
26.97 t ha⁻¹e6

Not reportedComparator

Verbatim

e0

“agronomic evaluation in sweet corn (Zea mays var. saccharata)”

✓ located verbatim in the source · abstract, characters 618–679 · show in text ↑
e6

“The hybrid formulation consisting of 60% UNS and 40% conventional urea (P6) achieved the highest productivity of 26.97 t ha⁻¹”

✓ located verbatim in the source · abstract, characters 1168–1293 · show in text ↑
Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

The P6 hybrid (60% UNS and 40% conventional urea) raised productivity by 9.2% compared with conventional urea alone.

Taxon
sweet corne0
Treatment
hybrid formulation consisting of 60% UNS and 40% conventional urea (P6)e6
Outcome
productivitye6
Direction
increasee7
Value
9.2%e7
Qualifier
24.71 t ha⁻¹e7
Comparator
conventional urea treatment alonee7

Verbatim

e0

“agronomic evaluation in sweet corn (Zea mays var. saccharata)”

✓ located verbatim in the source · abstract, characters 618–679 · show in text ↑
e6

“The hybrid formulation consisting of 60% UNS and 40% conventional urea (P6) achieved the highest productivity of 26.97 t ha⁻¹”

✓ located verbatim in the source · abstract, characters 1168–1293 · show in text ↑
e7

“representing a 9.2% increase compared with the conventional urea treatment alone (24.71 t ha⁻¹)”

✓ located verbatim in the source · abstract, characters 1296–1391 · show in text ↑
Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

The P6 hybrid raised productivity by 30.7% relative to the 100% UNS treatment.

Taxon
sweet corne0
Treatment
hybrid formulation consisting of 60% UNS and 40% conventional urea (P6)e6
Outcome
productivitye6
Direction
increasee7
Value
30.7%e7
Qualifier
20.64 t ha⁻¹e7
Comparator
100% UNS treatmente7

Verbatim

e0

“agronomic evaluation in sweet corn (Zea mays var. saccharata)”

✓ located verbatim in the source · abstract, characters 618–679 · show in text ↑
e6

“The hybrid formulation consisting of 60% UNS and 40% conventional urea (P6) achieved the highest productivity of 26.97 t ha⁻¹”

✓ located verbatim in the source · abstract, characters 1168–1293 · show in text ↑
e7

“a 30.7% increase relative to the 100% UNS treatment (20.64 t ha⁻¹)”

✓ located verbatim in the source · abstract, characters 1396–1462 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

The UNF-based hybrid treatment produced sweet corn yields of up to 25.73 t/ha.

Taxon
sweet corne0
Treatment
UNF-based hybrid treatmente1
Outcome
yieldse1
Value
25.73 t ha⁻¹e1

Verbatim

e0

“agronomic evaluation in sweet corn (Zea mays var. saccharata)”

✓ located verbatim in the source · abstract, characters 618–679 · show in text ↑
e1

“Similarly, the UNF-based hybrid treatment produced yields of up to 25.73 t ha⁻¹”

✓ located verbatim in the source · abstract, characters 1464–1543 · show in text ↑
Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

Nano urea application enhanced chlorophyll content, leaf thickness and nitrogen uptake efficiency in sweet corn.

Taxon
sweet corne0
Treatment
Nano urea applicatione1
Outcome
chlorophyll content, leaf thickness, and nitrogen uptake efficiencye1
Direction
enhancede1

Not reportedComparator

Verbatim

e0

“agronomic evaluation in sweet corn (Zea mays var. saccharata)”

✓ located verbatim in the source · abstract, characters 618–679 · show in text ↑
e1

“Nano urea application also enhanced chlorophyll content, leaf thickness, and nitrogen uptake efficiency”

✓ located verbatim in the source · abstract, characters 1546–1649 · show in text ↑
Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

Standalone UNF had the highest nitrogen-use efficiency, 90.95%, in sweet corn.

Taxon
sweet corne0
Treatment
standalone UNFe1
Outcome
NUEe1
Direction
higheste1
Value
90.95%e1

Not reportedComparator

Verbatim

e0

“agronomic evaluation in sweet corn (Zea mays var. saccharata)”

✓ located verbatim in the source · abstract, characters 618–679 · show in text ↑
e1

“standalone UNF exhibited the highest NUE (90.95%)”

✓ located verbatim in the source · abstract, characters 1660–1709 · show in text ↑
Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

UNS, through a more sustained nitrogen release, promoted biomass accumulation and yield formation in sweet corn.

Taxon
sweet corne0
Treatment
UNSe1
Outcome
biomass accumulation and yield formatione1
Direction
promotede1
Qualifier
more sustained nitrogen releasee1

Not reportedComparator

Verbatim

e0

“agronomic evaluation in sweet corn (Zea mays var. saccharata)”

✓ located verbatim in the source · abstract, characters 618–679 · show in text ↑
e1

“UNS provided a more sustained nitrogen release that promoted biomass accumulation and yield formation”

✓ located verbatim in the source · abstract, characters 1779–1880 · show in text ↑
Mechanismauthor interpretationoriginal resultpositivebasis n/a

Claim · model-written summary

The authors attribute the improved agronomic performance of sweet corn to enhanced surface interactions, controlled nutrient release and reduced nitrogen loss.

Taxon
sweet corne0
Outcome
agronomic performancee1
Qualifier
enhanced surface interactions, controlled nutrient release, and reduced nitrogen losse1

Verbatim

e0

“agronomic evaluation in sweet corn (Zea mays var. saccharata)”

✓ located verbatim in the source · abstract, characters 618–679 · show in text ↑
e1

“The improved agronomic performance was attributed to enhanced surface interactions, controlled nutrient release, and reduced nitrogen loss”

✓ located verbatim in the source · abstract, characters 1882–2020 · show in text ↑
Intervention effectobservedoriginal resultno effectmeasured

Claim · model-written summary

The hybrid nano urea strategy allowed a 60% reduction in conventional urea without compromising sweet corn productivity.

Taxon
sweet corne0
Treatment
hybrid nano urea strategye1
Outcome
productivitye1
Direction
without compromisinge1
Value
60% reductione1
Comparator
conventional urea applicatione1

Verbatim

e0

“agronomic evaluation in sweet corn (Zea mays var. saccharata)”

✓ located verbatim in the source · abstract, characters 618–679 · show in text ↑
e1

“the hybrid nano urea strategy enabled a 60% reduction in conventional urea application without compromising productivity”

✓ located verbatim in the source · abstract, characters 2035–2155 · show in text ↑

Zea mays subsp. mays · yield · Zea mays (maize)Results differ

292 papers: 196 positive, 96 negative or no effect

195 papers in the same direction as this paper · 85 in the opposite direction · 11 reporting no difference from an alternative

  1. no effect
  2. no effect
  3. negative

288 papers more in this group

See all 292 papers →

Zea mays subsp. mays · growth · Zea mays (maize)Positive and negative results

94 papers: 60 positive, 34 negative or no effect

33 papers in the same direction as this paper · 60 in the opposite direction

  1. positive
  2. positive
  3. positive

90 papers more in this group

See all 94 papers →

physical treatment · growth · Zea mays (maize)Results differ

9 papers: 6 positive, 3 negative or no effect

2 papers in the same direction as this paper · 6 in the opposite direction

  1. positive
  2. positive
  3. positive

5 papers more in this group

See all 9 papers →

nanoparticle · physiology: pigments · Zea mays (maize)Positive and negative results

50 papers: 44 positive, 6 negative or no effect

43 papers in the same direction as this paper · 5 in the opposite direction · 1 reporting no difference from an alternative

  1. negative
  2. negative
  3. negative

46 papers more in this group

See all 50 papers →

nitrogen · physiology: pigments · Zea mays (maize)Positive and negative results

126 papers: 112 positive, 14 negative or no effect

111 papers in the same direction as this paper · 13 in the opposite direction · 1 reporting no difference from an alternative

  1. negative
  2. negative
  3. no effect

122 papers more in this group

See all 126 papers →

nanoparticle · growth · Zea mays (maize)Positive and negative results

182 papers: 161 positive, 21 negative or no effect

20 papers in the same direction as this paper · 161 in the opposite direction

  1. positive
  2. positive
  3. positive

178 papers more in this group

See all 182 papers →

nitrogen · nutrient: efficiency · Zea mays (maize)Positive and negative results

194 papers: 142 positive, 52 negative or no effect

141 papers in the same direction as this paper · 42 in the opposite direction · 10 reporting no difference from an alternative

  1. negative
  2. negative
  3. no effect

190 papers more in this group

See all 194 papers →

nanoparticle · yield · Zea mays (maize)Positive and negative results

233 papers: 215 positive, 18 negative or no effect

214 papers in the same direction as this paper · 11 in the opposite direction · 7 reporting no difference from an alternative

  1. no effect
  2. positive
  3. positive

229 papers more in this group

See all 233 papers →

8 of 11 groups shown: named compounds and organisms first, then groups whose results differ (checked claim by claim), then those with positive and negative results, then the smaller groups.

Claims are grouped by organism, treatment and what was measured or targeted. A paper counts as positive when any of its claims in the group is positive.