Paper · 1996 · Environmental Science & Technology

Mimicked In-Situ Stabilization of Metals in a Cropped Soil: Bioavailability and Chemical Form of Zinc

Anna Chlopecka; Domy C. Adriano

11
claims
13
verbatim quotes
196
citations
2
research areas
—
Not open access

Abstract

Agricultural lime, natural zeolite (clinoptilolite), hydroxyapatite, and an iron oxide waste byproduct (Fe-rich, a trademark name of E. I. du Pont de Nemours) were added to an artificially contaminated Appling silt loam soil to stabilize and limit the uptake of Zn by crops. A greenhouse pot study involved spiking the soil with flue dust (FD) at 0, 150, 300, 600, 1200, and 2400 mg of Zn kg - 1 . As much as 40% of the total Zn occurred in an exchangeable form, the form considered most bioavailable to plants, when the pH of the FD-spiked soil was below 6.0. The ameliorants (lime, zeolite, apatite, and Fe-rich) decreased the concentration of the exchangeable form of Zn at each level of FD in soil; however, the largest decrease occurred with the lowest dose. Maize ( Zea mays ), barley ( Hordeum vulgare ), and radish ( Raphanus sativus ) were grown to determine the effects of Zn on the plant growth and its uptake. The addition of ameliorants to soil enhanced the growth and yield of maize and barley, but only Fe-rich enhanced the growth of radish at all FD rates. Lime, zeolite, and apatite significantly reduced the Zn concentration in tissues of the 3-week-old maize, in mature maize tissues (roots, young leaves, old leaves, stems, grain), and in barley. The largest reduction (over 80%) in Zn uptake by all crops was effected by Fe-rich, which is consistent with the greatest reduction in soil-exchangeable Zn by this ameliorant.

Abstract from the paper’s OpenAlex record, shown for indexing and research. Copyright remains with the authors or the publisher. Read at the source ↗

The text the model read, with the source record’s inline markup (italics, sub- and superscripts) rendered and its character entities decoded; quote offsets refer to the raw text.

Claims 11

Observationobservedoriginal resultmeasured

Claim · model-written summary

Up to 40% of soil Zn was exchangeable below pH 6.0.

Outcome
total Zn occurred in an exchangeable forme0
Value
40%e0
Qualifier
pH of the FD-spiked soil was below 6.0e0

Not reportedTaxon

Verbatim

e0

“As much as 40% of the total Zn occurred in an exchangeable form, the form considered most bioavailable to plants, when the pH of the FD-spiked soil was below 6.0”

✓ located verbatim in the source · abstract, characters 398–559 · show in text ↑
Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

Each ameliorant decreased exchangeable soil Zn at each FD level, with the largest decrease at the lowest dose.

Taxon
MaizeZea mayse1
Treatment
ameliorants (lime, zeolite, apatite, and Fe-rich)e0
Outcome
concentration of the exchangeable form of Zne0
Direction
decreasede0
Qualifier
largest decrease occurred with the lowest dosee0

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Zea mays
Zea mays · TaxonAkwugo · CC BY-SA 4.0 · Wikimedia Commons ↗

Verbatim

e0

“The ameliorants (lime, zeolite, apatite, and Fe-rich) decreased the concentration of the exchangeable form of Zn at each level of FD in soil; however, the largest decrease occurred with the lowest dose”

✓ located verbatim in the source · abstract, characters 561–762 · show in text ↑
e1

“Maize ( Zea mays ), barley ( Hordeum vulgare ), and radish ( Raphanus sativus )”

✓ located verbatim in the source · abstract, characters 764–843 · show in text ↑
Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

Ameliorants enhanced maize growth and yield.

Taxon
maizeZea mayse0
Treatment
addition of ameliorants to soile0
Outcome
growth and yielde0
Direction
enhancede0

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Zea mays
Zea mays · TaxonAkwugo · CC BY-SA 4.0 · Wikimedia Commons ↗

Verbatim

e0

“The addition of ameliorants to soil enhanced the growth and yield of maize and barley”

✓ located verbatim in the source · abstract, characters 922–1007 · show in text ↑
Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

Ameliorants enhanced barley growth and yield.

Treatment
addition of ameliorants to soile0
Outcome
growth and yielde0
Direction
enhancede0

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Hordeum vulgare
Hordeum vulgare · TaxonJackyM59 · CC BY-SA 4.0 · Wikimedia Commons ↗

Verbatim

e0

“The addition of ameliorants to soil enhanced the growth and yield of maize and barley”

✓ located verbatim in the source · abstract, characters 922–1007 · show in text ↑
Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

Only Fe-rich enhanced radish growth at all FD rates.

Treatment
Fe-riche0
Outcome
growthe0
Direction
enhancede0
Qualifier
at all FD ratese0

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Raphanus sativus
Raphanus sativus · TaxonSelf, en:User:Jengod · Public domain · Wikimedia Commons ↗

Verbatim

e0

“only Fe-rich enhanced the growth of radish at all FD rates”

✓ located verbatim in the source · abstract, characters 1013–1071 · show in text ↑
Intervention effectobservedoriginal resultpositivesignificant (as stated)measured

Claim · model-written summary

Lime significantly reduced Zn concentration in young maize tissues.

Taxon
maizeZea mayse0
Treatment
Limee0
Outcome
Zn concentration in tissues of the 3-week-old maizee0
Direction
reducede0

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Zea mays
Zea mays · TaxonAkwugo · CC BY-SA 4.0 · Wikimedia Commons ↗

Verbatim

e0

“Lime, zeolite, and apatite significantly reduced the Zn concentration in tissues of the 3-week-old maize, in mature maize tissues (roots, young leaves, old leaves, stems, grain), and in barley”

✓ located verbatim in the source · abstract, characters 1073–1265 · show in text ↑
Intervention effectobservedoriginal resultpositivesignificant (as stated)measured

Claim · model-written summary

Zeolite significantly reduced Zn concentration in young maize tissues.

Taxon
maizeZea mayse0
Treatment
zeolitee0
Outcome
Zn concentration in tissues of the 3-week-old maizee0
Direction
reducede0

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Zea mays
Zea mays · TaxonAkwugo · CC BY-SA 4.0 · Wikimedia Commons ↗

Verbatim

e0

“Lime, zeolite, and apatite significantly reduced the Zn concentration in tissues of the 3-week-old maize”

✓ located verbatim in the source · abstract, characters 1073–1177 · show in text ↑
Intervention effectobservedoriginal resultpositivesignificant (as stated)measured

Claim · model-written summary

Apatite significantly reduced Zn concentration in young maize tissues.

Taxon
maizeZea mayse0
Treatment
apatitee0
Outcome
Zn concentration in tissues of the 3-week-old maizee0
Direction
reducede0

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Zea mays
Zea mays · TaxonAkwugo · CC BY-SA 4.0 · Wikimedia Commons ↗

Verbatim

e0

“Lime, zeolite, and apatite significantly reduced the Zn concentration in tissues of the 3-week-old maize”

✓ located verbatim in the source · abstract, characters 1073–1177 · show in text ↑
Intervention effectobservedoriginal resultpositivesignificant (as stated)measured

Claim · model-written summary

Lime, zeolite and apatite significantly reduced Zn concentration in mature maize tissues.

Taxon
maizeZea mayse0
Organ / stage
mature maize tissues (roots, young leaves, old leaves, stems, grain)e0
Treatment
Lime, zeolite, and apatitee0
Outcome
Zn concentratione0
Direction
reducede0

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Zea mays
Zea mays · TaxonAkwugo · CC BY-SA 4.0 · Wikimedia Commons ↗

Verbatim

e0

“Lime, zeolite, and apatite significantly reduced the Zn concentration in tissues of the 3-week-old maize, in mature maize tissues (roots, young leaves, old leaves, stems, grain), and in barley”

✓ located verbatim in the source · abstract, characters 1073–1265 · show in text ↑
Intervention effectobservedoriginal resultpositivesignificant (as stated)measured

Claim · model-written summary

Lime, zeolite and apatite significantly reduced Zn concentration in barley.

Treatment
Lime, zeolite, and apatitee0
Outcome
Zn concentratione0
Direction
reducede0

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Hordeum vulgare
Hordeum vulgare · TaxonJackyM59 · CC BY-SA 4.0 · Wikimedia Commons ↗

Verbatim

e0

“Lime, zeolite, and apatite significantly reduced the Zn concentration in tissues of the 3-week-old maize, in mature maize tissues (roots, young leaves, old leaves, stems, grain), and in barley”

✓ located verbatim in the source · abstract, characters 1073–1265 · show in text ↑
Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

Fe-rich reduced crop Zn uptake by over 80%, the largest reduction.

Taxon
MaizeZea mayse1
Treatment
Fe-riche0
Outcome
Zn uptakee0
Direction
reductione0
Value
over 80%e0
Qualifier
all cropse0

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Zea mays
Zea mays · TaxonAkwugo · CC BY-SA 4.0 · Wikimedia Commons ↗

Verbatim

e0

“The largest reduction (over 80%) in Zn uptake by all crops was effected by Fe-rich”

✓ located verbatim in the source · abstract, characters 1267–1349 · show in text ↑
e1

“Maize ( Zea mays ), barley ( Hordeum vulgare ), and radish ( Raphanus sativus )”

✓ located verbatim in the source · abstract, characters 764–843 · show in text ↑

lime · molecular: metabolites · Zea mays (maize)Positive and negative results

13 papers: 8 positive, 5 negative or no effect

7 papers in the same direction as this paper · 5 in the opposite direction

  1. negative
  2. no effect
  3. negative

9 papers more in this group

See all 13 papers →

other · nutrient: content · Hordeum vulgare (barley)Positive and negative results

19 papers: 15 positive, 4 negative or no effect

14 papers in the same direction as this paper · 4 in the opposite direction

  1. negative
  2. no effect
  3. no effect

15 papers more in this group

See all 19 papers →

other · molecular: metabolites · Zea mays (maize)Positive and negative results

39 papers: 37 positive, 2 negative or no effect

36 papers in the same direction as this paper · 2 in the opposite direction

  1. no effect
  2. no effect
  3. positive

35 papers more in this group

See all 39 papers →

lime · nutrient: content · Zea mays (maize)Positive and negative results

95 papers: 71 positive, 24 negative or no effect

70 papers in the same direction as this paper · 24 in the opposite direction

  1. negative
  2. negative
  3. no effect

91 papers more in this group

See all 95 papers →

other · nutrient: content · Zea mays (maize)Positive and negative results

119 papers: 107 positive, 12 negative or no effect

106 papers in the same direction as this paper · 9 in the opposite direction · 3 reporting no difference from an alternative

  1. negative
  2. negative
  3. negative

115 papers more in this group

See all 119 papers →

lime · nutrient: content · Hordeum vulgare (barley)Results agree

14 papers: 14 positive, 0 negative or no effect

13 papers in the same direction as this paper

  1. positive
  2. positive
  3. positive

10 papers more in this group

See all 14 papers →

Claims are grouped by organism, treatment and what was measured or targeted. A paper counts as positive when any of its claims in the group is positive.