Paper · 2025 · Insects

Relative Effectiveness of Amorphous Silica, Malathion, and Pirimiphos Methyl in Controlling Sitophilus oryzae and Tribolium castaneum and Their Long-Term Effects on Stored Wheat Under Laboratory Conditions

Nawal Abdulaziz Alfuhaid; Mohamed S. Shawir

11
claims
23
verbatim quotes
0
citations
1
research areas
✓
Open access · cc-by

Abstract

The relative efficacy of amorphous silica dusts, malathion, and pirimiphos methyl was assessed against S. oryzae and T. castaneum in stored wheat under laboratory conditions. Insecticidal performance was influenced by physical properties such as particle size, surface area, bulk density, and oil/water adsorption capacity. Fumed silicas showed the highest toxicity, particularly Wacker HDK H20 (LC50 = 19.4 mg/100 g at 12% moisture). Precipitated silica, Sipernat 22, though less potent (LC50 = 46.6 mg/100 g), displayed consistent efficacy across different moisture levels, making it a suitable inert carrier. Increasing grain moisture to 15% significantly reduced the effectiveness of all dusts. When insecticides were combined with silica, their toxicity increased markedly. Malathion on silica (0.2%) reduced LC50 values to 21.5 and 23.3 µg a.i./100 g for T. castaneum and S. oryzae, respectively, compared to 52.3 and 84.7 µg a.i./100 g on talc. Pirimiphos methyl on silica (0.1%) was the most effective, achieving LC50 values of 13.4 and 15.5 µg a.i./100 g. Long-term bioassays over 25 weeks showed declining mortality rates, particularly at 15% moisture. However, pirimiphos methyl on silica maintained over 90% mortality at 12% moisture throughout the period, indicating strong residual efficacy. The results highlight the synergistic potential of combining silica with chemical insecticides and the crucial role of environmental humidity in stored grain pest management.

Abstract from the paper’s OpenAlex record; open copy licensed cc-by. Read at the source ↗

The text the model read, with the source record’s inline markup (italics, sub- and superscripts) rendered and its character entities decoded; quote offsets refer to the raw text.

Claims 11

Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

Fumed silicas showed the highest toxicity to the stored-grain pests.

Treatment
Fumed silicase1
Interactor
S. oryzaeSitophilus oryzaee0pest
Second interactor
T. castaneumTribolium castaneume0pest
Outcome
toxicitye1
Direction
higheste1

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Triticum aestivum
Triticum aestivum · TaxonRasbak · CC BY-SA 3.0 · Wikimedia Commons ↗
Sitophilus oryzae
Sitophilus oryzae · Interactorpicture taken by Olaf Leillinger · CC BY-SA 2.5 · Wikimedia Commons ↗
Tribolium castaneum
Tribolium castaneum · Second interactorPublic domain · Wikimedia Commons ↗

Verbatim

e0

“The relative efficacy of amorphous silica dusts, malathion, and pirimiphos methyl was assessed against S. oryzae and T. castaneum in stored wheat under laboratory conditions”

✓ located verbatim in the source · abstract, characters 0–173 · show in text ↑
e1

“Fumed silicas showed the highest toxicity, particularly Wacker HDK H20 (LC50 = 19.4 mg/100 g at 12% moisture)”

✓ located verbatim in the source · abstract, characters 324–433 · show in text ↑
Observationobservedoriginal resultpositivemeasured

Claim · model-written summary

Wacker HDK H20 had an LC50 of 19.4 mg/100 g at 12% moisture.

Treatment
Wacker HDK H20e1
Interactor
S. oryzaeSitophilus oryzaee0pest
Second interactor
T. castaneumTribolium castaneume0pest
Outcome
LC50e1
Value
19.4 mg/100 ge1
Qualifier
at 12% moisturee1

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Triticum aestivum
Triticum aestivum · TaxonRasbak · CC BY-SA 3.0 · Wikimedia Commons ↗
Sitophilus oryzae
Sitophilus oryzae · Interactorpicture taken by Olaf Leillinger · CC BY-SA 2.5 · Wikimedia Commons ↗
Tribolium castaneum
Tribolium castaneum · Second interactorPublic domain · Wikimedia Commons ↗

Verbatim

e0

“The relative efficacy of amorphous silica dusts, malathion, and pirimiphos methyl was assessed against S. oryzae and T. castaneum in stored wheat under laboratory conditions”

✓ located verbatim in the source · abstract, characters 0–173 · show in text ↑
e1

“Fumed silicas showed the highest toxicity, particularly Wacker HDK H20 (LC50 = 19.4 mg/100 g at 12% moisture)”

✓ located verbatim in the source · abstract, characters 324–433 · show in text ↑
Observationobservedoriginal resultnegativemeasured

Claim · model-written summary

Sipernat 22 was less potent than the fumed silicas, with an LC50 of 46.6 mg/100 g.

Treatment
Sipernat 22e2
Interactor
S. oryzaeSitophilus oryzaee0pest
Second interactor
T. castaneumTribolium castaneume0pest
Outcome
LC50e2
Value
46.6 mg/100 ge2
Qualifier
less potente2

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Triticum aestivum
Triticum aestivum · TaxonRasbak · CC BY-SA 3.0 · Wikimedia Commons ↗
Sitophilus oryzae
Sitophilus oryzae · Interactorpicture taken by Olaf Leillinger · CC BY-SA 2.5 · Wikimedia Commons ↗
Tribolium castaneum
Tribolium castaneum · Second interactorPublic domain · Wikimedia Commons ↗

Verbatim

e0

“The relative efficacy of amorphous silica dusts, malathion, and pirimiphos methyl was assessed against S. oryzae and T. castaneum in stored wheat under laboratory conditions”

✓ located verbatim in the source · abstract, characters 0–173 · show in text ↑
e2

“Precipitated silica, Sipernat 22, though less potent (LC50 = 46.6 mg/100 g)”

✓ located verbatim in the source · abstract, characters 435–510 · show in text ↑
Observationobservedoriginal resultpositivemeasured

Claim · model-written summary

Sipernat 22 showed consistent efficacy across different moisture levels.

Treatment
Sipernat 22e2
Interactor
S. oryzaeSitophilus oryzaee0pest
Second interactor
T. castaneumTribolium castaneume0pest
Outcome
efficacye3
Qualifier
across different moisture levelse3

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Triticum aestivum
Triticum aestivum · TaxonRasbak · CC BY-SA 3.0 · Wikimedia Commons ↗
Sitophilus oryzae
Sitophilus oryzae · Interactorpicture taken by Olaf Leillinger · CC BY-SA 2.5 · Wikimedia Commons ↗
Tribolium castaneum
Tribolium castaneum · Second interactorPublic domain · Wikimedia Commons ↗

Verbatim

e0

“The relative efficacy of amorphous silica dusts, malathion, and pirimiphos methyl was assessed against S. oryzae and T. castaneum in stored wheat under laboratory conditions”

✓ located verbatim in the source · abstract, characters 0–173 · show in text ↑
e2

“Precipitated silica, Sipernat 22, though less potent (LC50 = 46.6 mg/100 g)”

✓ located verbatim in the source · abstract, characters 435–510 · show in text ↑
e3

“displayed consistent efficacy across different moisture levels”

✓ located verbatim in the source · abstract, characters 512–574 · show in text ↑
Intervention effectobservedoriginal resultnegativesignificant (as stated)measured

Claim · model-written summary

Increasing grain moisture to 15% significantly reduced the effectiveness of all dusts.

Treatment
Increasing grain moisture to 15%e4
Interactor
S. oryzaeSitophilus oryzaee0pest
Second interactor
T. castaneumTribolium castaneume0pest
Outcome
effectivenesse4
Direction
reducede4

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Triticum aestivum
Triticum aestivum · TaxonRasbak · CC BY-SA 3.0 · Wikimedia Commons ↗
Sitophilus oryzae
Sitophilus oryzae · Interactorpicture taken by Olaf Leillinger · CC BY-SA 2.5 · Wikimedia Commons ↗
Tribolium castaneum
Tribolium castaneum · Second interactorPublic domain · Wikimedia Commons ↗

Verbatim

e0

“The relative efficacy of amorphous silica dusts, malathion, and pirimiphos methyl was assessed against S. oryzae and T. castaneum in stored wheat under laboratory conditions”

✓ located verbatim in the source · abstract, characters 0–173 · show in text ↑
e4

“Increasing grain moisture to 15% significantly reduced the effectiveness of all dusts”

✓ located verbatim in the source · abstract, characters 612–697 · show in text ↑
Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

Combining insecticides with silica markedly increased their toxicity.

Treatment
insecticides were combined with silicae5
Interactor
S. oryzaeSitophilus oryzaee0pest
Second interactor
T. castaneumTribolium castaneume0pest
Outcome
toxicitye5
Direction
increasede5
Qualifier
markedlye5

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Triticum aestivum
Triticum aestivum · TaxonRasbak · CC BY-SA 3.0 · Wikimedia Commons ↗
Sitophilus oryzae
Sitophilus oryzae · Interactorpicture taken by Olaf Leillinger · CC BY-SA 2.5 · Wikimedia Commons ↗
Tribolium castaneum
Tribolium castaneum · Second interactorPublic domain · Wikimedia Commons ↗

Verbatim

e0

“The relative efficacy of amorphous silica dusts, malathion, and pirimiphos methyl was assessed against S. oryzae and T. castaneum in stored wheat under laboratory conditions”

✓ located verbatim in the source · abstract, characters 0–173 · show in text ↑
e5

“When insecticides were combined with silica, their toxicity increased markedly”

✓ located verbatim in the source · abstract, characters 699–777 · show in text ↑
Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

Malathion on silica (0.2%) reduced LC50 values to 21.5 and 23.3 µg a.i./100 g, compared with 52.3 and 84.7 µg a.i./100 g on talc.

Treatment
Malathion on silica (0.2%)e6
Interactor
T. castaneumTribolium castaneume6pest
Second interactor
S. oryzaeSitophilus oryzaee6pest
Outcome
LC50 valuese6
Direction
reducede6
Value
21.5 and 23.3 µg a.i./100 ge6
Qualifier
52.3 and 84.7 µg a.i./100 g on talce6
Comparator
talce6

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Triticum aestivum
Triticum aestivum · TaxonRasbak · CC BY-SA 3.0 · Wikimedia Commons ↗
Tribolium castaneum
Tribolium castaneum · InteractorPublic domain · Wikimedia Commons ↗
Sitophilus oryzae
Sitophilus oryzae · Second interactorpicture taken by Olaf Leillinger · CC BY-SA 2.5 · Wikimedia Commons ↗

Verbatim

e0

“The relative efficacy of amorphous silica dusts, malathion, and pirimiphos methyl was assessed against S. oryzae and T. castaneum in stored wheat under laboratory conditions”

✓ located verbatim in the source · abstract, characters 0–173 · show in text ↑
e6

“Malathion on silica (0.2%) reduced LC50 values to 21.5 and 23.3 µg a.i./100 g for T. castaneum and S. oryzae, respectively, compared to 52.3 and 84.7 µg a.i./100 g on talc”

✓ located verbatim in the source · abstract, characters 779–950 · show in text ↑
Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

Pirimiphos methyl on silica (0.1%) was the most effective treatment, with LC50 values of 13.4 and 15.5 µg a.i./100 g.

Treatment
Pirimiphos methyl on silica (0.1%)e7
Interactor
S. oryzaeSitophilus oryzaee0pest
Second interactor
T. castaneumTribolium castaneume0pest
Outcome
LC50 valuese7
Value
13.4 and 15.5 µg a.i./100 ge7
Qualifier
the most effectivee7

Not reportedComparatorDirection

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Triticum aestivum
Triticum aestivum · TaxonRasbak · CC BY-SA 3.0 · Wikimedia Commons ↗
Sitophilus oryzae
Sitophilus oryzae · Interactorpicture taken by Olaf Leillinger · CC BY-SA 2.5 · Wikimedia Commons ↗
Tribolium castaneum
Tribolium castaneum · Second interactorPublic domain · Wikimedia Commons ↗

Verbatim

e0

“The relative efficacy of amorphous silica dusts, malathion, and pirimiphos methyl was assessed against S. oryzae and T. castaneum in stored wheat under laboratory conditions”

✓ located verbatim in the source · abstract, characters 0–173 · show in text ↑
e7

“Pirimiphos methyl on silica (0.1%) was the most effective, achieving LC50 values of 13.4 and 15.5 µg a.i./100 g”

✓ located verbatim in the source · abstract, characters 952–1063 · show in text ↑
Associationobservedoriginal resultnegativemeasured

Claim · model-written summary

Mortality rates in long-term bioassays declined over 25 weeks, particularly at 15% moisture.

Outcome
mortality ratese1
Direction
declininge1
Qualifier
over 25 weekse1
Setting
15% moisturee1

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Triticum aestivum
Triticum aestivum · TaxonRasbak · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“The relative efficacy of amorphous silica dusts, malathion, and pirimiphos methyl was assessed against S. oryzae and T. castaneum in stored wheat under laboratory conditions”

✓ located verbatim in the source · abstract, characters 0–173 · show in text ↑
e1

“Long-term bioassays over 25 weeks showed declining mortality rates, particularly at 15% moisture”

✓ located verbatim in the source · abstract, characters 1065–1161 · show in text ↑
Observationobservedoriginal resultpositivemeasured

Claim · model-written summary

Pirimiphos methyl on silica maintained over 90% mortality at 12% moisture throughout the period.

Treatment
pirimiphos methyl on silicae1
Outcome
mortalitye1
Value
over 90%e1
Qualifier
throughout the periode1
Setting
12% moisturee1

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Triticum aestivum
Triticum aestivum · TaxonRasbak · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“The relative efficacy of amorphous silica dusts, malathion, and pirimiphos methyl was assessed against S. oryzae and T. castaneum in stored wheat under laboratory conditions”

✓ located verbatim in the source · abstract, characters 0–173 · show in text ↑
e1

“However, pirimiphos methyl on silica maintained over 90% mortality at 12% moisture throughout the period”

✓ located verbatim in the source · abstract, characters 1163–1267 · show in text ↑
Associationobservedoriginal resultmeasured

Claim · model-written summary

Insecticidal performance was influenced by physical properties of the dusts, such as particle size, surface area, bulk density and oil/water adsorption capacity.

Treatment
physical properties such as particle size, surface area, bulk density, and oil/water adsorption capacitye1
Outcome
Insecticidal performancee1

Not reportedDirection

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Triticum aestivum
Triticum aestivum · TaxonRasbak · CC BY-SA 3.0 · Wikimedia Commons ↗

Verbatim

e0

“The relative efficacy of amorphous silica dusts, malathion, and pirimiphos methyl was assessed against S. oryzae and T. castaneum in stored wheat under laboratory conditions”

✓ located verbatim in the source · abstract, characters 0–173 · show in text ↑
e1

“Insecticidal performance was influenced by physical properties such as particle size, surface area, bulk density, and oil/water adsorption capacity”

✓ located verbatim in the source · abstract, characters 175–322 · show in text ↑

silicon dioxide · Sitophilus oryzae · Triticum aestivum (wheat)Positive and negative results

2 papers: 1 positive, 1 negative or no effect

1 in the opposite direction

  1. negative
See all 2 papers →

malathion · Tribolium castaneum · Triticum aestivum (wheat)Positive and negative results

4 papers: 3 positive, 1 negative or no effect

2 papers in the same direction as this paper · 1 in the opposite direction

  1. negative
  2. positive
  3. positive
See all 4 papers →

pirimiphos-methyl · Sitophilus oryzae · Triticum aestivum (wheat)Results agree

2 papers: 2 positive, 0 negative or no effect

1 paper in the same direction as this paper

  1. positive
See all 2 papers →

insecticide · Sitophilus oryzae · Triticum aestivum (wheat)Positive and negative results

2 papers: 1 positive, 1 negative or no effect

1 in the opposite direction

  1. negative
See all 2 papers →

Claims are grouped by organism, treatment and what was measured or targeted. A paper counts as positive when any of its claims in the group is positive.