Paper · 2021 · Food Chemistry X

Optimization of extraction conditions and determination of the Chlorpyrifos, Diazinon, and malathion residues in environment samples: Fruit (Apple, Orange, and Tomato)

Giti Kashi; Nafiseh Nourieh; Parisa Mostashari; et al.

17
claims
24
verbatim quotes
13
citations
2
research areas
✓
Open access · cc-by-nc-nd

Abstract

Organophosphate (OP) insecticide, such as diazinon is found in the environments like water which is still approved for agricultural uses. When diazinon residues enter the human body, it functions as an acetylcholinesterase (AChE) inhibitor. This research aims to measure of chlorpyrifos (CPF), diazinon, and malathion residues in fruit such as apple, orange, and tomato after optimizing extraction conditions. Pesticide residues are measured by gas chromatography (GC) technique. Effective variables on pesticide residues are studied including pesticides kind, sampling station, and fruit kind. Results show that average concentration CPF, diazinon, and malathion residues in orange water are 7.05 ± 0.01 mg L−1, 6.66 ± 0.03 mg L−1, and 12.38 ± 0.02 µgL−1, respectively. The average concentration CPF, diazinon, and malathion residues in apple water are 0.74 ± 0.02 mgL−1, 0.70 ± 0.01 mgL−1, and 1.10 ± 0.01 µgL−1, respectively. The average concentration CPF, diazinon, and malathion residues in tomato water are 0.60 ± 0.02 mgL−1, 0.57 ± 0.02 mgL−1, and 0.89 ± 0.01 µgL−1, respectively. The highest CPF concentration is observed in the orange fruit from station 20. Due to an appropriate storage condition and presenting organic fruits in the supermarket, the least mean concentration of pesticides is obtained in studied fruits from station 2. The manner of washing, peeling, and storage period before consuming fruits lead to decreasing studied pesticides concentration about 15–35, 40–50, and 50–60%, respectively. Increasing the fruit shelf-life led to decreasing studied pesticides concentration. Between pesticide concentration and variables: pesticides kind, sampling station, fruit kind, are not seen meaningful statistic relationship (P > 0.05). This study showed that pesticide residues in fruits can be decreased by washing, refrigerating, peeling procedures and increase in public surveillance.

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Claims 17

Observationobservedoriginal resultmeasured

Claim · model-written summary

Orange water contained an average chlorpyrifos concentration of 7.05 ± 0.01 mg L−1.

Taxon
orangee0
Outcome
CPFe0
Value
7.05 ± 0.01 mg L−1e0

Verbatim

e0

“average concentration CPF, diazinon, and malathion residues in orange water are 7.05 ± 0.01 mg L−1, 6.66 ± 0.03 mg L−1, and 12.38 ± 0.02 µgL−1, respectively”

✓ located verbatim in the source · abstract, characters 613–769 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

Orange water contained an average diazinon concentration of 6.66 ± 0.03 mg L−1.

Taxon
orangee0
Outcome
diazinone0
Value
6.66 ± 0.03 mg L−1e0

Verbatim

e0

“average concentration CPF, diazinon, and malathion residues in orange water are 7.05 ± 0.01 mg L−1, 6.66 ± 0.03 mg L−1, and 12.38 ± 0.02 µgL−1, respectively”

✓ located verbatim in the source · abstract, characters 613–769 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

Orange water contained an average malathion concentration of 12.38 ± 0.02 µgL−1.

Taxon
orangee0
Outcome
malathion residuese0
Value
12.38 ± 0.02 µgL−1e0

Verbatim

e0

“average concentration CPF, diazinon, and malathion residues in orange water are 7.05 ± 0.01 mg L−1, 6.66 ± 0.03 mg L−1, and 12.38 ± 0.02 µgL−1, respectively”

✓ located verbatim in the source · abstract, characters 613–769 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

Apple water contained an average chlorpyrifos concentration of 0.74 ± 0.02 mgL−1.

Outcome
CPFe0
Value
0.74 ± 0.02 mgL−1e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Malus domestica
Malus domestica · TaxonW.carter · CC0 · Wikimedia Commons ↗

Verbatim

e0

“average concentration CPF, diazinon, and malathion residues in apple water are 0.74 ± 0.02 mgL−1, 0.70 ± 0.01 mgL−1, and 1.10 ± 0.01 µgL−1, respectively”

✓ located verbatim in the source · abstract, characters 775–927 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

Apple water contained an average diazinon concentration of 0.70 ± 0.01 mgL−1.

Outcome
diazinone0
Value
0.70 ± 0.01 mgL−1e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Malus domestica
Malus domestica · TaxonW.carter · CC0 · Wikimedia Commons ↗

Verbatim

e0

“average concentration CPF, diazinon, and malathion residues in apple water are 0.74 ± 0.02 mgL−1, 0.70 ± 0.01 mgL−1, and 1.10 ± 0.01 µgL−1, respectively”

✓ located verbatim in the source · abstract, characters 775–927 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

Apple water contained an average malathion concentration of 1.10 ± 0.01 µgL−1.

Outcome
malathion residuese0
Value
1.10 ± 0.01 µgL−1e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Malus domestica
Malus domestica · TaxonW.carter · CC0 · Wikimedia Commons ↗

Verbatim

e0

“average concentration CPF, diazinon, and malathion residues in apple water are 0.74 ± 0.02 mgL−1, 0.70 ± 0.01 mgL−1, and 1.10 ± 0.01 µgL−1, respectively”

✓ located verbatim in the source · abstract, characters 775–927 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

Tomato water contained an average chlorpyrifos concentration of 0.60 ± 0.02 mgL−1.

Outcome
CPFe0
Value
0.60 ± 0.02 mgL−1e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Solanum lycopersicum
Solanum lycopersicum · TaxonKod B · CC BY-SA 4.0 · Wikimedia Commons ↗

Verbatim

e0

“average concentration CPF, diazinon, and malathion residues in tomato water are 0.60 ± 0.02 mgL−1, 0.57 ± 0.02 mgL−1, and 0.89 ± 0.01 µgL−1, respectively”

✓ located verbatim in the source · abstract, characters 933–1086 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

Tomato water contained an average diazinon concentration of 0.57 ± 0.02 mgL−1.

Outcome
diazinone0
Value
0.57 ± 0.02 mgL−1e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Solanum lycopersicum
Solanum lycopersicum · TaxonKod B · CC BY-SA 4.0 · Wikimedia Commons ↗

Verbatim

e0

“average concentration CPF, diazinon, and malathion residues in tomato water are 0.60 ± 0.02 mgL−1, 0.57 ± 0.02 mgL−1, and 0.89 ± 0.01 µgL−1, respectively”

✓ located verbatim in the source · abstract, characters 933–1086 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

Tomato water contained an average malathion concentration of 0.89 ± 0.01 µgL−1.

Outcome
malathion residuese0
Value
0.89 ± 0.01 µgL−1e0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Solanum lycopersicum
Solanum lycopersicum · TaxonKod B · CC BY-SA 4.0 · Wikimedia Commons ↗

Verbatim

e0

“average concentration CPF, diazinon, and malathion residues in tomato water are 0.60 ± 0.02 mgL−1, 0.57 ± 0.02 mgL−1, and 0.89 ± 0.01 µgL−1, respectively”

✓ located verbatim in the source · abstract, characters 933–1086 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

The highest fruit chlorpyrifos concentration occurred in orange at station 20.

Taxon
orangee0
Outcome
CPF concentratione0
Direction
higheste0
Setting
station 20e0

Verbatim

e0

“The highest CPF concentration is observed in the orange fruit from station 20”

✓ located verbatim in the source · abstract, characters 1088–1165 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

Fruits from station 2 had the lowest mean pesticide concentration.

Taxon
Apple, Orange, and Tomatot0
Outcome
concentration of pesticidese0
Direction
leaste0
Setting
station 2e0

Verbatim

t0

“Fruit (Apple, Orange, and Tomato)”

✓ located verbatim in the source · title, characters 134–167 · show in text ↑
e0

“the least mean concentration of pesticides is obtained in studied fruits from station 2”

✓ located verbatim in the source · abstract, characters 1257–1344 · show in text ↑
Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

Washing decreased pesticide concentrations in the studied fruits by about 15–35%.

Taxon
Apple, Orange, and Tomatot0
Treatment
washinge0
Outcome
studied pesticides concentratione0
Direction
decreasinge0
Value
15–35e0

Not reportedComparator

Verbatim

t0

“Fruit (Apple, Orange, and Tomato)”

✓ located verbatim in the source · title, characters 134–167 · show in text ↑
e0

“The manner of washing, peeling, and storage period before consuming fruits lead to decreasing studied pesticides concentration about 15–35, 40–50, and 50–60%, respectively”

✓ located verbatim in the source · abstract, characters 1346–1517 · show in text ↑
Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

Peeling decreased pesticide concentrations in the studied fruits by about 40–50%.

Taxon
Apple, Orange, and Tomatot0
Treatment
peelinge0
Outcome
studied pesticides concentratione0
Direction
decreasinge0
Value
40–50e0

Not reportedComparator

Verbatim

t0

“Fruit (Apple, Orange, and Tomato)”

✓ located verbatim in the source · title, characters 134–167 · show in text ↑
e0

“The manner of washing, peeling, and storage period before consuming fruits lead to decreasing studied pesticides concentration about 15–35, 40–50, and 50–60%, respectively”

✓ located verbatim in the source · abstract, characters 1346–1517 · show in text ↑
Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

A longer storage period decreased pesticide concentrations in the studied fruits by about 50–60%.

Taxon
Apple, Orange, and Tomatot0
Treatment
storage periode0
Outcome
studied pesticides concentratione0
Direction
decreasinge0
Value
50–60%e0

Not reportedComparator

Verbatim

t0

“Fruit (Apple, Orange, and Tomato)”

✓ located verbatim in the source · title, characters 134–167 · show in text ↑
e0

“The manner of washing, peeling, and storage period before consuming fruits lead to decreasing studied pesticides concentration about 15–35, 40–50, and 50–60%, respectively”

✓ located verbatim in the source · abstract, characters 1346–1517 · show in text ↑
Associationobservedoriginal resultpositivemeasured

Claim · model-written summary

Increased fruit shelf life was associated with lower pesticide concentrations.

Taxon
Apple, Orange, and Tomatot0
Organ / stage
fruite0
Outcome
studied pesticides concentratione0
Direction
decreasinge0
Qualifier
Increasing the fruit shelf-lifee0

Verbatim

t0

“Fruit (Apple, Orange, and Tomato)”

✓ located verbatim in the source · title, characters 134–167 · show in text ↑
e0

“Increasing the fruit shelf-life led to decreasing studied pesticides concentration”

✓ located verbatim in the source · abstract, characters 1519–1601 · show in text ↑
Associationobservedoriginal resultno effectnot significant (as stated)measured

Claim · model-written summary

Pesticide concentration had no statistically meaningful association with pesticide kind, sampling station, or fruit kind.

Taxon
Apple, Orange, and Tomatot0
Outcome
pesticide concentratione0
Qualifier
pesticides kind, sampling station, fruit kinde0
Setting
sampling statione0

Not reportedDirection

Verbatim

t0

“Fruit (Apple, Orange, and Tomato)”

✓ located verbatim in the source · title, characters 134–167 · show in text ↑
e0

“Between pesticide concentration and variables: pesticides kind, sampling station, fruit kind, are not seen meaningful statistic relationship (P > 0.05)”

✓ located verbatim in the source · abstract, characters 1603–1754 · show in text ↑
Recommendationauthor interpretationoriginal resultpositivebasis n/a

Claim · model-written summary

The authors recommend washing, refrigeration, peeling, and greater public surveillance to lower fruit pesticide residues.

Taxon
Apple, Orange, and Tomatot0
Outcome
pesticide residues in fruits can be decreased by washing, refrigerating, peeling procedures and increase in public surveillancee0

Verbatim

t0

“Fruit (Apple, Orange, and Tomato)”

✓ located verbatim in the source · title, characters 134–167 · show in text ↑
e0

“pesticide residues in fruits can be decreased by washing, refrigerating, peeling procedures and increase in public surveillance”

✓ located verbatim in the source · abstract, characters 1779–1906 · show in text ↑

processing · molecular: metabolites · Citrus sinensis (sweet orange)Positive and negative results

7 papers: 5 positive, 2 negative or no effect

4 papers in the same direction as this paper · 2 in the opposite direction

  1. no effect
  2. negative
  3. positive

3 papers more in this group

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processing · molecular: metabolites · Solanum lycopersicum (tomato)Positive and negative results

23 papers: 16 positive, 7 negative or no effect

15 papers in the same direction as this paper · 7 in the opposite direction

  1. no effect
  2. negative
  3. negative

19 papers more in this group

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storage · molecular: metabolites · Solanum lycopersicum (tomato)Positive and negative results

25 papers: 19 positive, 6 negative or no effect

18 papers in the same direction as this paper · 6 in the opposite direction

  1. no effect
  2. negative
  3. negative

21 papers more in this group

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processing · molecular: metabolites · Malus domestica (apple)Positive and negative results

25 papers: 16 positive, 9 negative or no effect

15 papers in the same direction as this paper · 7 in the opposite direction · 2 reporting no difference from an alternative

  1. no effect
  2. no effect
  3. negative

21 papers more in this group

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storage · molecular: metabolites · Malus domestica (apple)Positive and negative results

38 papers: 21 positive, 17 negative or no effect

20 papers in the same direction as this paper · 16 in the opposite direction · 1 reporting no difference from an alternative

  1. negative
  2. no effect
  3. negative

34 papers more in this group

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storage · molecular: metabolites · Citrus sinensis (sweet orange)Results agree

4 papers: 4 positive, 0 negative or no effect

3 papers in the same direction as this paper

  1. positive
  2. positive
  3. positive
See all 4 papers →

Claims are grouped by organism, treatment and what was measured or targeted. A paper counts as positive when any of its claims in the group is positive.