Paper · 2025 · Postharvest Biology and Technology

Effect of long-term controlled atmosphere storage enriched with ethanol or hexanal vapour on primary and secondary aroma compounds of ‘Braeburn’ and ‘Granny Smith’ apples

Erika Jesenko; Rajko Vidrih; Emil Zlatić

6
claims
10
verbatim quotes
3
citations
2
research areas
✓
Open access · cc-by

Abstract

The aim of this research was to study the effects of ethanol or hexanal enriched atmosphere focusing on primary (PA) and secondary aroma (SA) volatiles of 'Braeburn' and 'Granny Smith' apples. Apples were stored for 7 months under three conditions: controlled atmosphere (CA, 2 kPa O 2 ,1 kPa CO 2 ), CA with hexanal or CA with ethanol vapour (55 µgL −1 air). Volatile profiles were analyzed over 7 days of shelf-life at 20 °C. The results showed large differences between PA and SA profiles. The SA of both cultivars showed higher levels of aldehydes and alcohols, while PA was characterized by higher contents of hexyl and butyl esters. The most influential compounds were hexyl 2-methylbutanoate, hexanal, and 2-methylbutanal for 'Braeburn', and 2-methyl-1-butanol, butanal, and hexanal for 'Granny Smith' apples. The effect of the addition of hexanal and ethanol to CA on the PA and SA profile after storage was dependent on the cultivar and shelf-life period. The most pronounced effect was observed with hexanal treatment on the PA of ‘Braeburn’ apples, where hexanal treatment enhanced key aroma-active compounds, such as hexyl butanoate and hexyl hexanoate. Both vapor treatments induced the formation of 2-pentanone and 2-pentanol, indicating lipid peroxidation in both apple cultivars. Prolonged exposure to ethanol or hexanal vapors in CA can modulate the synthesis of key volatile compounds in PA and SA, potentially offering promising applications in the flavor and food industries. • Multivariate analyses were performed to identify volatile marker compounds. • Primary aroma was characterized by higher levels of hexyl and butyl esters. • Secondary aroma had higher levels of aldehydes, alcohols, and ethyl esters. • Volatile compound differences identified after ethanol and hexanal storage treatments.

Abstract from the paper’s OpenAlex record; open copy licensed cc-by. Read at the source ↗

The text the model read, with the source record’s inline markup (italics, sub- and superscripts) rendered and its character entities decoded; quote offsets refer to the raw text.

Claims 6

Observationobservedoriginal resultmeasured

Claim · model-written summary

Secondary aroma had higher aldehydes and alcohols than primary aroma.

Material
both cultivarse0
Outcome
aldehydes and alcoholse0
Direction
highere0
Comparator
PAe0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Malus domestica
Malus domestica · TaxonW.carter · CC0 · Wikimedia Commons ↗

Verbatim

e0

“The SA of both cultivars showed higher levels of aldehydes and alcohols, while PA was characterized by higher contents of hexyl and butyl esters.”

✓ located verbatim in the source · abstract, characters 493–638 · show in text ↑
t0

“apples”

✓ located verbatim in the source · title, characters 164–170 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

Primary aroma had higher hexyl and butyl ester contents than secondary aroma.

Outcome
hexyl and butyl esterse0
Direction
highere0
Comparator
SAe0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Malus domestica
Malus domestica · TaxonW.carter · CC0 · Wikimedia Commons ↗

Verbatim

e0

“The SA of both cultivars showed higher levels of aldehydes and alcohols, while PA was characterized by higher contents of hexyl and butyl esters.”

✓ located verbatim in the source · abstract, characters 493–638 · show in text ↑
t0

“apples”

✓ located verbatim in the source · title, characters 164–170 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

The influential Braeburn volatiles were three named compounds.

Material
'Braeburn'e0
Outcome
hexyl 2-methylbutanoate, hexanal, and 2-methylbutanale0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Malus domestica
Malus domestica · TaxonW.carter · CC0 · Wikimedia Commons ↗

Verbatim

e0

“The most influential compounds were hexyl 2-methylbutanoate, hexanal, and 2-methylbutanal for 'Braeburn'”

✓ located verbatim in the source · abstract, characters 639–743 · show in text ↑
t0

“apples”

✓ located verbatim in the source · title, characters 164–170 · show in text ↑
Observationobservedoriginal resultmeasured

Claim · model-written summary

The influential Granny Smith volatiles were three named compounds.

Material
'Granny Smith'e0
Outcome
2-methyl-1-butanol, butanal, and hexanale0

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Malus domestica
Malus domestica · TaxonW.carter · CC0 · Wikimedia Commons ↗

Verbatim

e0

“2-methyl-1-butanol, butanal, and hexanal for 'Granny Smith' apples”

✓ located verbatim in the source · abstract, characters 749–815 · show in text ↑
Intervention effectobservedoriginal resultpositivemeasured

Claim · model-written summary

Hexanal treatment enhanced two key aroma compounds in Braeburn primary aroma.

Material
‘Braeburn’t0
Treatment
hexanal treatmente0
Outcome
hexyl butanoate and hexyl hexanoatee0
Direction
enhancede0

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Malus domestica
Malus domestica · TaxonW.carter · CC0 · Wikimedia Commons ↗

Verbatim

e0

“hexanal treatment enhanced key aroma-active compounds, such as hexyl butanoate and hexyl hexanoate”

✓ located verbatim in the source · abstract, characters 1066–1164 · show in text ↑
t0

“‘Braeburn’ and ‘Granny Smith’ apples”

✓ located verbatim in the source · title, characters 134–170 · show in text ↑
Intervention effectobservedoriginal resultmeasured

Claim · model-written summary

Both vapour treatments induced 2-pentanone and 2-pentanol in apples.

Treatment
Both vapor treatmentse0
Outcome
formation of 2-pentanone and 2-pentanole0
Direction
inducede0

Not reportedComparator

Organisms pictured · Representative pictures of the matched species, not figures from the paper.

Malus domestica
Malus domestica · TaxonW.carter · CC0 · Wikimedia Commons ↗

Verbatim

e0

“Both vapor treatments induced the formation of 2-pentanone and 2-pentanol, indicating lipid peroxidation in both apple cultivars.”

✓ located verbatim in the source · abstract, characters 1166–1295 · show in text ↑

hexanal · molecular: metabolites · Malus domestica (apple)Results agree

2 papers: 2 positive, 0 negative or no effect

1 paper in the same direction as this paper

  1. positive
See all 2 papers →

Claims are grouped by organism, treatment and what was measured or targeted. A paper counts as positive when any of its claims in the group is positive.